全文获取类型
收费全文 | 17881篇 |
免费 | 2169篇 |
国内免费 | 2966篇 |
专业分类
化学 | 11297篇 |
晶体学 | 162篇 |
力学 | 2061篇 |
综合类 | 254篇 |
数学 | 5878篇 |
物理学 | 3364篇 |
出版年
2024年 | 42篇 |
2023年 | 242篇 |
2022年 | 325篇 |
2021年 | 586篇 |
2020年 | 708篇 |
2019年 | 645篇 |
2018年 | 611篇 |
2017年 | 693篇 |
2016年 | 833篇 |
2015年 | 609篇 |
2014年 | 818篇 |
2013年 | 1639篇 |
2012年 | 1029篇 |
2011年 | 1030篇 |
2010年 | 908篇 |
2009年 | 1118篇 |
2008年 | 1127篇 |
2007年 | 1203篇 |
2006年 | 1005篇 |
2005年 | 933篇 |
2004年 | 870篇 |
2003年 | 748篇 |
2002年 | 699篇 |
2001年 | 577篇 |
2000年 | 566篇 |
1999年 | 517篇 |
1998年 | 417篇 |
1997年 | 355篇 |
1996年 | 321篇 |
1995年 | 320篇 |
1994年 | 253篇 |
1993年 | 239篇 |
1992年 | 175篇 |
1991年 | 158篇 |
1990年 | 103篇 |
1989年 | 77篇 |
1988年 | 80篇 |
1987年 | 61篇 |
1986年 | 59篇 |
1985年 | 63篇 |
1984年 | 53篇 |
1983年 | 28篇 |
1982年 | 36篇 |
1981年 | 34篇 |
1980年 | 30篇 |
1979年 | 28篇 |
1978年 | 8篇 |
1977年 | 16篇 |
1976年 | 7篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
The purpose of this article is to investigate high‐order numerical approximations of scalar conservation laws with nonlocal viscous term. The viscous term is given in the form of convolution in space variable. With the help of the characteristic of viscous term, we design a semidiscrete local discontinuous Galerkin (LDG) method to solve the nonlocal model. We prove stability and convergence of semidiscrete LDG method in L2 norm. The theoretical analysis reveals that the present numerical scheme is stable with optimal convergence order for the linear case, and it is stable with sub‐optimal convergence order for nonlinear case. To demonstrate the validity and accuracy of our scheme, we test the Burgers equation with two typical nonlocal fractional viscous terms. The numerical results show the convergence order accuracy in space for both linear and nonlinear cases. Some numerical simulations are provided to show the robustness and effectiveness of the present numerical scheme. 相似文献
12.
采用溶剂热法,1,3,5-三(羧基甲氧基)苯为定向配体和乙酸镍反应构筑了一个新型的金属配位聚合物[Ni(TB)2(H2O)2]n·2H2O,其中H3TB=1,3,5-三(羧基甲氧基)苯,通过元素分析、IR及X射线单晶衍射对配合物结构进行表征,并研究其荧光性质、热稳定性及Hirshfeld表面作用力。单晶结构分析表明,该配合物属于三斜晶系,空间群$P \overline{1}$,配合物中心离子Ni(Ⅱ)分别与来自两个水分子上的氧原子及四个不同1,3,5-三(羧基甲氧基)苯配体的羧酸氧原子配位,形成六配位的NiO6八面体构型,并通过与1,3,5-三(羧基甲氧基)苯配体的氧原子配位不断延伸形成具有孔洞结构的一维链状构型。配合物具有良好的荧光性能和热稳定性。Hirshfeld表面作用分析表明配合物分子中O…H/H…O作用占主导且占比为39.0%,而H…H的作用力占比为25.9%,O…O的作用力占比为13.6%。 相似文献
13.
K-g-框架是将算子K引入到g-框架中的一种特殊框架.采用泛函分析中的技巧和方法,研究K-g-框架的稳定性,并得到了四个K-g-框架在扰动情况下稳定的充分条件.此外,结合算子K和框架算子S衍生出K-g-框架的三个等式,并通过引入参数λ建立关于K-g-框架的一些不等式. 相似文献
14.
15.
16.
This study investigated the effects of different treatment of alkaline pH-shifting on milk protein concentrate (MPC), micellar casein concentrate (MCC) and whey protein isolate (WPI) assisted by the same ultrasound conditions, including changes in the physicochemical properties, solubility and foaming capacity. The solubility of milk proteins had a significant increase with gradual enhancement of ultrasound-assisted alkaline pH-shifting (p < 0.05), especially for MCC up to 99.50 %. Also, treatment made a significant decline in the particle size of MPC and MCC, as well as the turbidity of the proteins (p < 0.05). The foaming capacity of MPC, MCC, and WPI was all improved, especially at pH 11, and at this pH, the milk protein also showed the highest surface hydrophobicity. The best foaming capacity at pH 11 was the result of the combined effect of particle size, potential, protein conformation, solubility, and surface hydrophobicity. In conclusion, ultrasound-assisted pH-shifting treatment was found to be effective in improving the physicochemical properties and solubility and foaming capacity of milk proteins, especially MCC, with promising application prospect in food industry. 相似文献
17.
Mossel and Ross raised the question of when a random coloring of a graph can be reconstructed from local information, namely, the colorings (with multiplicity) of balls of given radius. In this article, we are concerned with random 2-colorings of the vertices of the -dimensional hypercube, or equivalently random Boolean functions. In the worst case, balls of diameter are required to reconstruct. However, the situation for random colorings is dramatically different: we show that almost every 2-coloring can be reconstructed from the multiset of colorings of balls of radius 2. Furthermore, we show that for , almost every -coloring can be reconstructed from the multiset of colorings of 1-balls. 相似文献
18.
Dr. Celina Sikorska 《Chemphyschem》2019,20(17):2236-2246
Superhalogens, owing to their large electron affinity (EA, exceeding those of any halogen atom), play an essential role in physical chemistry as well as new material design. They have applications in hydrogen storage and lithium-ion batteries. Owing to the unique geometries and electronic features of magnesium-based clusters, their potential to form a new class of lithium salts has been investigated here theoretically. The idea is assessed by conducting ab initio computations on Li+/MgnF2n+1-2mOm− compounds (n=2, 3; m=0-3) and analyzing their performance as potential Li-ion battery electrolytes. The Mg3F7− cluster, with large electron binding energy (EA of 7.93 eV), has been proven to serve as a building block for lithium salts. It is shown that, apart from high electronic stability, the new superhalogen-based electrolytes exhibit a set of desirable properties, including a large band gap, high electrolyte stability window, easy mobility of the Li+, and favorable insensitivity to water. 相似文献
19.
为明确超声共振频谱分析法(RUS)测定圆柱体试样弹性常数的影响因素, 由此针对各向同性圆柱体开展实验, 观察圆柱体试样测量结果的分散性和稳定性, 且主要研究横纵比和有效模态数量对测量结果的影响, 并与拉伸试验的结果进行比较. 以测量结果标准差、变异系数和95%置信度下均值的区间估计3个指标来衡量结果的稳定性和分散性, 且从模态简并角度对实验结果进行分析. 最终结果表明, 当超声共振频谱分析法的有效模态数量在17左右、试样横纵比接近1时, 测量结果的稳定性和分散性较小. 相似文献
20.